74246-27-8Relevant academic research and scientific papers
Efficient and regioselective ruthenium-catalyzed hydro-aminomethylation of olefins
Wu, Lipeng,Fleischer, Ivana,Jackstell, Ralf,Beller, Matthias
supporting information, p. 3989 - 3996 (2013/04/10)
An efficient and regioselective ruthenium-catalyzed hydroaminomethlyation of olefins is reported. Key to success is the use of specific 2-phosphino-substituted imidazole ligands and triruthenium dodecacarbonyl as catalyst. Both industrially important alip
Amines made easily: A highly selective hydroaminomethylation of olefins
Ahmed, Moballigh,Seayad, Abdul Majeed,Jackstell, Ralf,Beller, Matthias
, p. 10311 - 10318 (2007/10/03)
A highly chemo- and regioselective hydroaminomethylation of simple as well as functionalized α-olefins using a cationic rhodium precatalyst together with Xantphos as ligand is reported. Studies of the influence of ligands and reaction conditions led to an unprecedented selective hydroaminomethylation procedure. The novel procedure constitutes an economically attractive and environmentally favorable synthesis of secondary and tertiary aliphatic amines.
