74279-87-1

Upstream product

• 110-89-4 piperidine 

Downstream Products

• 98977-36-7 3-oxo-piperidine-1-carboxylic acid tert-butyl ester 
• 61995-20-8 N-(benzyloxycarbonyl)-3-piperidone 
• 383430-26-0 {(1R,2S)-2-[(S)-3-(4-Fluoro-benzyl)-piperidin-1-ylmethyl]-cyclohexyl}-carbamic acid benzyl ester 
• 275815-63-9 (1R,2S)-2-(((S)-3-(4-fluorobenzyl)piperidin-1-yl)methyl)cyclohexylamine 
• 109-00-2 3-HYDROXYPYRIDINE 
• 1270019-64-1 1-(7-tosyl-7H-pyrrolo[2,3-d]pyrimidin-4-yl)piperidin-3-one 
• 1270015-17-2 N-(2-(1-(7H-pyrrolo[2,3-d]pyrimidin-4-yl)piperidin-3-ylamino)-2-oxoethyl)-2-chlorobenzamide 
• 1270019-66-3 N-benzyl-2-(phenylamino)-N-(1-(7-tosyl-7H-pyrrolo[2,3-d]pyrimidin-4-yl)piperidin-3-yl)acetamide 
• 1270019-65-2 N-benzyl-1-(7-tosyl-7H-pyrrolo[2,3-d]pyrimidin-4-yl)piperidin-3-amine 
• 1270015-11-6 N-(1-(7H-pyrrolo[2,3-d]pyrimidin-4-yl)piperidin-3-yl)-N-benzyl-2-(phenylamino)acetamide 
• 98977-38-9 ethyl (+/-)-1-(tert-butyloxycarbonyl)-3-oxoperhydroazepine-4-carboxylate 

Relevant academic research and scientific papers

Iron-catalyzed oxidative functionalization of C(sp3)-H bonds under bromide-synergized mild conditions

An efficient oxidation and functionalization of C-H bonds with an inorganic-ligand supported iron catalyst and hydrogen peroxide to prepare the corresponding ketones was achieved using the bromide ion as a promoter. Preliminary mechanistic investigations indicated that the bromide ion can bind to FeMo6 to form a supramolecular species (FeMo6·2Br), which can effectively catalyze the reaction.