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7429-49-4

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7429-49-4 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 7429-49-4 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 7,4,2 and 9 respectively; the second part has 2 digits, 4 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 7429-49:
(6*7)+(5*4)+(4*2)+(3*9)+(2*4)+(1*9)=114
114 % 10 = 4
So 7429-49-4 is a valid CAS Registry Number.

7429-49-4Downstream Products

7429-49-4Relevant articles and documents

Oxidation of some vicinal and non-vicinal diols by morpholinium chlorochromate: A kinetic and mechanistic study

Barthora,Baghmar,Agarwal,Sharma, Vinita

experimental part, p. 677 - 683 (2012/04/10)

The kinetics of oxidation of four vicinal, four non-vicinal diols and two of their monoethers by morpholinium chlorochromate (MCC) have been studied in dimethylsulphoxide (DMSO). The main product of oxidation is the corresponding hydroxycarbonyl compound. The reaction is first order in MCC and the diols. The reaction is catalysed by hydrogen ions. The hydrogen ion dependence is taking the form : kobs = a + b [H+]. The oxidation of [1,1,2,2-2H4]ethanediol exhibits a substantial primary kinetic isotope effect (kH/kD = 5.82 at 298 K). The reaction has been studied in nineteen different organic solvents and the solvent effect has been analysed using Taft's and Swain's multiparametric equations. The temperature dependence of the kinetic isotope effect indicates the presence of a symmetrical transition state in the rate-determining step. A suitable mechanism has been proposed.

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