743-67-9Relevant academic research and scientific papers
THERMAL DISSOCIATION OF DI(ALKYLBENZYL)NAPHTHYL>PEROXYDICARBONATES IN RELATION TO THE STRUCTURE OF THE ALKYL AROMATIC FRAGMENTS
Fomin, V. A.,Etlis, I. V.,Kurskii, Yu. A.,Nozrina, F. D.,Chervyakova, G. N.,Shmuilovich, S. M.
, p. 811 - 819 (2007/10/02)
The kinetics of the thermolysis of di peroxydicarbonates at 40-70 deg C in organic solvents were investigated, the effectiveness of escape of the free radicals from the solvent "cage" was studied, and the final products from thermal dissociation of the peroxydicarbonates were investigated.A scheme was formulated for the thermolysis of peroxides, explaining the relation between the homolysis rate of the O-O group and the reactivity of the obtained free radicals in relation to the structure of the alkylbenzyl fragments in the symmetrical and unsymmetrical peroxydicarbonates.
