74331-48-9Relevant articles and documents
Reactions of Isothiocyanates with Cyanothioformamides. Cyclization of 5-Imino-4-thioxo-2-imidazolidones and 5-Imino-2,4-imidazolidinedithiones to 5,7-Dihydrodiimidazopyrazine-2,6(1H,3H)-diones and -dithiones
Khattak, Ismail,Ketcham, Roger,Schaumann, Ernst,Adiwidjaja, Gunadi
, p. 3431 - 3434 (1985)
N-Methyl- or N-phenylcyanothioformamide (1a,b) reacts with methyl or phenyl isocyanate to provide 5-imino-1,3-disubstituted-4-thioxo-2-imidazolidinones 3a-d.Methyl or phenyl isothiocyanate with 1a,b gives 5-imino-1,3-disubstituted-2,4-imidazolidinedithion
Heterocyclic Ring-Closure Reactions. 6. Preparation and Further Cyclization Reactions of 5-Imino-1,3-diphenyl-4-thioxo-2-imidazolidinone and 5-Imino-1,3-diphenyl-2,4-imidazolidinedithione
Ketcham, Roger,Schaumann, Ernst
, p. 3748 - 3750 (2007/10/02)
Phenyl isocyanate (1a) and phenyl isothiocyanate (1b) react with cyanothioformanilide (2b) to give the title compounds 3b and 3c.With additional 1a, 3b,c provide the 5-(N-phenylcarbamoyl) derivatives 4b,c.With hydrochloric acid, 3b,c afford the 4-oxo comp