7438-77-9Relevant articles and documents
New Pyoverdin-Type Siderophores from Pseudomonas fluorescens
Mohn, G.,Taraz, K.,Budzikiewicz, H.
, p. 1437 - 1450 (2007/10/02)
The structures of two new pyoverdins (GM-I and GM-II) isolated from the culture medium of Pseudomonas fluorescens have been elucidated by spectroscopic methods and degradation studies.The pyoverdins consist of a chromophore which could be identified as (1S)-5-amino-2,3-dihydro-8,9-dihydroxy-1H-pyrimidoquinoline-1-carvoxylic acid substituted at the amino group with 3-carboxypropanoyl or a siccinamoyl residue and at the carboxy group with the N-terminus of D-Ala-D-Lys-Gly-Gly-D-threo-(OH)Asp-D-Glu-D-Ser-L-Ala-D-Ala-L-Ala-L-N5-(OH)Orn.According to the "short-hand" nomenclatur proposed in the two compounds should be characterized as pyoverdin-X-akGGd'qsAaaAO'*-SUCA and pyoverdin-Q-akGGD'qaAaaAO'*-SUC.