74403-68-2Relevant articles and documents
Enantioselective stereoinversion in the kinetic resolution of rac-sec-alkyl sulfate esters by hydrolysis with an alkylsulfatase from Rhodococcus ruber DSM 44541 furnishes homochiral products
Pogorevc, Mateja,Kroutil, Wolfgang,Wallner, Sabine R.,Faber, Kurt
, p. 4052 - 4054 (2002)
The biocatalytic hydrolysis of (±)-sec-alkyl sulfate esters with an alkylsulfatase from Rhodococcus ruber DSM 44541 proceeded with high enantioselectivity (up to 99% ee) and with absolute stereoselectivity through inversion of configuration. Thus, a rac substrate was converted into homochiral S-configured products (see scheme).