74404-26-5Relevant academic research and scientific papers
Novel reaction: Decarboxylative Bamberg-Backlung rearrangement in some α-isopropyl sulfonyl carboxylic esters
Wladislaw,Marzorati,Torres Russo,Zaim,Di Vitta
, p. 8367 - 8370 (2007/10/02)
The reaction of some isopropylsulfonyl α-mono and disubstituted esters with KOH/t-BuOH/CCl4 is reported. For the α,α-dialkyl and α-monoaryl substituted derivatives the key step of this reaction is proposed to be the decarboxylative 1,3-displacement in the chlorinated intermediates.
