74408-55-2

Basic information

• Product Name: Cyclohexene, 6-(1-butenyl)-1,5,5-trimethyl-, (E)-
• CAS NO: 74408-55-2
• Molecular Formula: C13H22
• Molecular Weight: 178.318
• Mol File: 74408-55-2.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Cyclohexene, 6-(1-butenyl)-1,5,5-trimethyl-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexene, 6-(1-butenyl)-1,5,5-trimethyl-, (E)-(74408-55-2)
• EPA Substance Registry System: Cyclohexene, 6-(1-butenyl)-1,5,5-trimethyl-, (E)-(74408-55-2)

Safety Data

• Hazardous Substances Data: 74408-55-2(Hazardous Substances Data)

Upstream product

• 25312-34-9 alpha-ionol 
• 783324-41-4 (2E)-1-methyl-3-(2,6,6-trimethyl-2-cyclohexen-1-yl)-2-propenyl acetate 
• 1071003-47-8 Phosphoric acid (E)-1-cyano-1-methyl-3-(2,6,6-trimethyl-cyclohex-2-enyl)-allyl ester diethyl ester 
• 16666-78-7 propylidenetriphenylphosphorane 
• 14505-74-9 α-cyclocitral 
• 127-41-3 alpha-ionone 

Relevant articles and documents

A novel reduction reaction for the conversion of aldehydes, ketones and primary, secondary and tertiary alcohols into their corresponding alkanes

A novel one-pot reaction has been developed for the reduction of aldehydes, ketones and primary, secondary and tertiary alcohols into their corresponding alkyl function. This is also the first reported method which can efficiently reduce primary, secondary, or tertiary alcohols, without affecting carbon-carbon double bonds, into their corresponding alkyl function in high yields. The reduction utilises either diethylsilane or n-butylsilane as the reducing agent in the presence of the Lewis acid catalyst tris(pentafluorophenyl)borane.

THE HYDRIDOPENTACYANOCOBALTATE ANION INDUCED DEOXYGENATION OF ALLYLIC ALCOHOLS USING β-CYCLODEXTRIN AS A PHASE TRANSFER AGENT

β-Cyclodextrin promotes the deoxygenation of allylic alcohols to olefins using hydrogen and the in situ generated hydridopentacyanocobaltate anion.Internal olefins, of trans-stereochemistry, are the principal reaction products (i. e., no cis-products are formed).

Reductive Displacement of the Acetate Group in Allyl, Propargyl, and Benzyl Acetates by NaBH4/NiCl2 * 6H2O

The combination of NiCl2 *6H2O and NaBH4 provides an effective system for reductive removal of the acetate group of allyl, propargyl, and benzyl acetates.Sterically less hindered allyl acetates are converted preferentially to the corresponding alkanes (Table 1).