74410-52-9

Upstream product

• 74410-53-0 Methyl 4,6-O-benzylidene-3-O-methyl-α-D-altropyranoside 

Downstream Products

• 134110-37-5 methyl 4,6-O-benzylidene-2-deoxy-2,2-difluoro-3-O-methyl-α-D-ribo-hexopyranoside 
• 74410-54-1 methyl 4,6-O-benzylidene-3-O-methyl-α-D-arabino-hexopyranosid-2-ulosee 

Relevant academic research and scientific papers

New Oxidative Systems for Alcohols: Molecular Sieves with Chromium (VI) Reagents

The oxidation of various kinds of alcohols, including carbohydrates and nucleosides, by molecular sieve-pyridinium chlorochromate and molecular sieve-pyridinium dichromate has been investigated.The catalytic properties of molecular sieves have been investigated using kinetic, stereochemical, and isotope-labelling experiments.It is postulated that specific sites on the sieves favour hydride-ion transfer.

Molecular Sieve-assisted Oxidations: New Methods for Carbohydrate Derivative Oxidations

Molecular sieves catalyse pyridinium chlorochromate and pyridinium dichromate oxidation and so give rise to an efficient synthesis of ketonucleosides and ketosugars at room temperature.