74438-95-2Relevant academic research and scientific papers
Does Substrate Rather Than Protein Provide the Catalyst for &α-Proton Abstraction in Aldolase?
Periana, R. A.,Motiu-DeGrood, Rossana,Chiang, Yvonne,Hupe, D. J.
, p. 3923 - 3927 (2007/10/02)
Dihydroxyacetone sulfate (DHAS) forms an iminium ion with rabbit muscle aldolase as does the natural substrate dihydroxyacetone phosphate (DHAP), but DHAS does not undergo subsequent α-proton abstraction to form enamine, as has been shown by Grazi.We prop
