74457-13-9Relevant academic research and scientific papers
ALDOL REACTION OF ALUMINIUM ENOLATE RESULTING FROM 1,4-ADDITION OF Me2AlSPh TO α,β-UNSATURATED CARBONYL COMPOUND. A 1-ACYLETHENYL ANION EQUIVALENT
Itoh, Akira,Ozawa, Shuji,Oshima, Koichiro,Nozaki, Hitosi
, p. 361 - 364 (1980)
Me2AlSPh or Me2AlSeMe adds to α,β-unsaturated carbonyl compounds in 1,4-fashion.The resulting aluminium enolates react with aldehydes effectively to afford the adducts of the title anion after formal PhSH (or MeSeH)-elimination
Aldol Reaction of Aluminium Enolate Resulting from 1,4-Addition of R2AlX to α,β-Unsaturated Carbonyl Compound. A 1-Acylethenyl Anion Equivalent
Itoh, Akira,Ozawa, Shuji,Oshima, Koichiro,Nozaki, Hitosi
, p. 274 - 278 (2007/10/02)
Organoaluminium reagents R2AlX (X=SPh, SeMe) easily add to α,β-unsaturated carbonyl compounds in 1,4-fashion.The resulting aluminium enolates react with aldehydes to give aldol adducts in fair to good yields.Formal elimination of HX from the adducts provi
