74481-11-1

Basic information

• Product Name: 2,2,2-trichloroethyl 6α-phenylselenylpenicillanate
• Synonyms: 2,2,2-trichloroethyl 6α-phenylselenylpenicillanate
• CAS NO: 74481-11-1
• Molecular Weight: 487.693
• Mol File: 74481-11-1.mol

Chemical Properties

• CAS DataBase Reference: 2,2,2-trichloroethyl 6α-phenylselenylpenicillanate(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2,2-trichloroethyl 6α-phenylselenylpenicillanate(74481-11-1)
• EPA Substance Registry System: 2,2,2-trichloroethyl 6α-phenylselenylpenicillanate(74481-11-1)

Safety Data

• Hazardous Substances Data: 74481-11-1(Hazardous Substances Data)

Upstream product

• 14370-82-2 allyl phenyl selenide 
• 51056-24-7 (2S,5R)-6-Diazo-3,3-dimethyl-7-oxo-4-thia-1-aza-bicyclo[3.2.0]heptane-2-carboxylic acid 2,2,2-trichloro-ethyl ester 
• 645-96-5 Benzeneselenol 
• 1666-13-3 diphenyl diselenide 
• 26774-86-7 2,2,2-trichloroethyl 6β-phenylacetamidopenicillanate 
• 51056-23-6 6β-(nitroso-phenylacetyl-amino)-penicillanic acid 2,2,2-trichloro-ethyl ester 

Relevant articles and documents

Preparation of 6α-Monosubstituted and 6,6-Disubstituted Penicillanates from 6-Diazopenicillanates: Reactions of 6-Diazopenicillanates with Alcohols, Thiols, Phenylseleninyl Compounds, and Allylic Sulphides, and their Analogues

Reactions of 6-diazapenicillanates (1) and (2) with a range of compounds, in some cases catalysed by BF3-Et2O or Cu(acac)2, have been investigated, and found to be useful for the synthesis of 6α-monosubstituted and 6,6-disubstituted penicillanates.Thus th

Preparation and reduction of 6-phenylselenylpenicillanates. A stereoselective synthesis of 6β-substituted penicillanates

The preparation and tri-n-butyltin hydride reduction of benzyl 6-chloro-6-phenyl-selenyl- and benzyl 6,6-bis(phenylselenyl)penicillanates, and related compounds, is discussed.