74491-80-8Relevant academic research and scientific papers
Branched-chain Sugars. Part 8. The Synthesis of C-Acetylpyranosides and a Pillarose Derivative using 1-Methoxyvinyl-lithium
Brimacombe, John S.,Hanna, Rod,Mather, Agnes M.,Weakley, Timothy J.R.
, p. 273 - 276 (2007/10/02)
1-Methoxyvinyl-lithium, a masked acylating agent, added to the protected hexopyranosiduloses (1), (4), and (7) to give adducts that were readily hydrolysed with acid to the C-acetyl derivatives (3), (6), and (9), respectively.The 1-methoxyvinyl adduct (13
