74500-98-4

Upstream product

• 74501-06-7 C₂₁H₃₄O₃ 
• 98-59-9 p-toluenesulfonyl chloride 
• 74501-02-3 C₂₃H₃₄O₅ 
• 74501-01-2 C₂₄H₃₆O₄ 
• 74501-05-6 C₂₃H₃₆O₃S₂ 
• 74501-03-4 C₂₃H₃₆O₅ 
• 74501-04-5 C₂₁H₃₂O₄ 
• 2651-32-3 (1R,4aS,8aS,10aR)-1,4a-Dimethyl-6-oxo-1,2,3,4,4a,6,7,8,8a,9,10,10a-dodecahydro-phenanthrene-1-carboxylic acid methyl ester 
• 85706-54-3 C₂₁H₃₂O₄ 
• 74501-02-3 C₂₃H₃₄O₅ 
• 74501-01-2 C₂₄H₃₆O₄ 
• 74501-05-6 C₂₃H₃₆O₃S₂ 
• 74501-03-4 C₂₃H₃₆O₅ 
• 74501-04-5 C₂₁H₃₂O₄ 

Downstream Products

• 56573-92-3 (+/-)-stemodinol 
• 41703-77-9 (+/-)-2-desoxystemodinone 

Relevant academic research and scientific papers

Total synthesis of the stemodane-type diterpenoids, (+/-)-2-desoxystemodinone, (+)-2-desoxystemodinone, and (+/-)-stemodinol

Stereospecific total syntheses of (+/-)-2-desoxystemodinone, (+)-2-desoxystemodinone, and (+/-)-stemodinol are described.Also described are the isolation of (+)-2-desoxystemodinone from S. maritima and its characterization.A strategy for the elaboration o

A total synthesis of (+/-)-stemarin, a diterpenoid with a unique bicyclic C/D ring system

A total synthesis of (+/-)-stemarin, a diterpenoid with a unique C/D ring system, is described.The synthesis features photoaddition of allene to an α,β-unsaturated ketone and two skeletal rearrangements.Application of the synthetic strategy described here