745013-67-6

Basic information

• Product Name: [Pd(SC₆F₄-4-H)2(1,1'-bis(diphenylphosphino)ferrocene)]
• CAS NO: 745013-67-6
• Molecular Weight: 1023.08
• Mol File: 745013-67-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Pd(SC₆F₄-4-H)2(1,1'-bis(diphenylphosphino)ferrocene)](CAS DataBase Reference)
• NIST Chemistry Reference: [Pd(SC₆F₄-4-H)2(1,1'-bis(diphenylphosphino)ferrocene)](745013-67-6)
• EPA Substance Registry System: [Pd(SC₆F₄-4-H)2(1,1'-bis(diphenylphosphino)ferrocene)](745013-67-6)

Safety Data

• Hazardous Substances Data: 745013-67-6(Hazardous Substances Data)

Upstream product

• 72287-26-4 (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride 

Relevant articles and documents

[1,1′-Bis(diphenylphosphino)ferrocene]palladium(II) complexes with fluorinated benzenethiolate ligands: Examination of the electronic effects in the solid state, solution and in the Pd-catalyzed Heck reaction with the catalytic system [Pd(dppf)(SRF)2]

A series of palladium thiolate complexes of the type [Pd(dppf) (SRF)2] have been synthesized in good yields by metathetical reactions of [Pd(dppf)Cl2] with [Pb(SRF)2], (SRF=- SC6F5, -SC6F4 -4-H, -SC6H4-2-CF3, -SC6H4-4-F, - SC6H4-3-F) and their crystal structures determined. The effect of the different thiolates in the structural properties of the complexes both in the solid state and in solution have been analyzed. Heck coupling reactions were carried out using the complexes [Pd(dppf)(SRF)2], SRF =-SC6F5 (1), -SC6 F4-4-H (2), -SC6H4 -2-CF3 (3), -SC6H4-4-F (4), -SC6H4-3-F (5) as catalysts in order to examine both the effect of the thiolates and the P-Pd-P bite angles in the reaction of bromobenzene and styrene. The results obtained indicate that electron-withdrawing substituents may favor higher yields in the Pd catalyzed Heck reaction using [Pd(dppf)(SRF) 2] as catalysts.