74503-39-2Relevant academic research and scientific papers
THE EFFECT OF THE STABILIZATION AND LOCALIZATION ENERGY ON THE REACTIVITY OF THE REAGENTS IN THE DIELS-ALDER REACTION
Konovalov, A. I.,Kiselev, V. D.
, p. 1018 - 1028 (2007/10/02)
The effect of the stabilization and localization energy on the reactivity of the addends in the Diels-Alder reaction was examined.The enthalpies of stabilization were calculated from data on the ionization potentials and electron affinities, and the chang
Reaktivity of Substituted 1,3-Butadienes in Diels-Alder-Reactions
Ruecker, Christa,Lang, Dietrich,Sauer, Juergen,Friege, Henning,Sustmann, Reiner
, p. 1663 - 1690 (2007/10/02)
Kinetic data for the reaction of substituted 1,3-dienes with tetracyanoethylene (TCNE) and other dienophiles are interpreted in terms of the FMO-model.While the expectations are fulfilled qualitatively, the kinetic data cannot be correlated quantitatively.This shows that in Diels-Alder reactions besides HOMO-LUMO separation other factors play an important role, for instance the 1,4-distance in the diene and the conformational equilibrium cisoid transoid of the diene.The kinetic data are in accord with a one-step mechanism of the cycloaddition reaction.
