745075-82-5Relevant academic research and scientific papers
Synthesis of tunable phosphinite-pyridine ligands and their applications in asymmetric hydrogenation
Liu, Qi-Bin,Yu, Chang-Bin,Zhou, Yong-Gui
, p. 4733 - 4736 (2007/10/03)
A new class of modular conformationally rigid N,P ligands is conveniently synthesized from readily available starting material. Iridium complexes with these ligands have demonstrated excellent enantioselectivity (up to 99% ee) in the asymmetric hydrogenation of aryl alkenes.
Synthesis and evaluation of new chiral nonracemic C2-symmetric and unsymmetric 2,2′-bipyridyl ligands
Lyle, Michael P.A.,Draper, Neil D.,Wilson, Peter D.
, p. 877 - 885 (2007/10/03)
The synthesis of a series of chiral nonracemic and C2-symmetric 2,2′-bipyridyl ligands (R = Me, i-Pr and Ph) as well as the syntheses of the corresponding unsymmetric 2,2′-bipyridyl ligands (R = Me and Ph) is described. These bipyridyl ligands
A new class of chiral P,N-ligands and their application in palladium-catalyzed asymmetric allylic substitution reactions
Lyle, Michael P. A.,Narine, Arun A.,Wilson, Peter D.
, p. 5060 - 5064 (2007/10/03)
An efficient and modular synthesis of a series of chiral nonracemic P,N-ligands is reported. The P,N-ligands were prepared from 2-chloro-4-methyl-6, 7-dihydro-5H-[1]pyrindine-7-one and a series of substituted chiral C 2-symmetric 1,2-ethanediol
