74581-67-2

Upstream product

• 74581-60-5 1-nitro-octan-3-one ethylene ketal 
• 74581-62-7 (Z)-(R)-8-{(4S,6S)-6-[1-Acetoxy-2-nitro-3-(2-pentyl-[1,3]dioxolan-2-yl)-propyl]-2,2-dimethyl-[1,3]dioxan-4-yl}-8-(tert-butyl-diphenyl-silanyloxy)-oct-5-enoic acid methyl ester 
• 74581-61-6 (Z)-(R)-8-(tert-Butyl-diphenyl-silanyloxy)-8-{(4S,6R)-6-[1-hydroxy-2-nitro-3-(2-pentyl-[1,3]dioxolan-2-yl)-propyl]-2,2-dimethyl-[1,3]dioxan-4-yl}-oct-5-enoic acid methyl ester 
• 74595-20-3 (Z)-(R)-8-(tert-Butyl-diphenyl-silanyloxy)-8-{(2S,4R)-4-hydroxy-5-[1-nitro-2-(2-pentyl-[1,3]dioxolan-2-yl)-ethyl]-tetrahydro-furan-2-yl}-oct-5-enoic acid methyl ester 
• 80102-63-2 (5Z,12E)-(8R,9S,11S)-8-(tert-Butyl-diphenyl-silanyloxy)-9,11-dihydroxy-13-nitro-14-(2-pentyl-[1,3]dioxolan-2-yl)-tetradeca-5,12-dienoic acid methyl ester 
• 74581-63-8 methyl 8R-tert-butyldiphenylsilyloxy-11R-hydroxy-13-nitro-15-oxo-9S,12S-oxyeicosa-5Z-enoate 
• 74581-58-1 methyl 8R-tert-butyldiphenylsilyloxy-9S,11R-dihydroxy-9,11-O-isopropylidene-12,12-di(ethylthio)dodeca-5Z-enoate 
• 74581-59-2 methyl 8R-tert-butyldiphenylsilyloxy-9S,11R-dihydroxy-9,11-O-isopropylidene-12-oxo-dodeca-5Z-enoate 
• 74595-17-8 (Z)-(8R,9S,11R)-8-(tert-Butyl-diphenyl-silanyloxy)-12,12-bis-ethylsulfanyl-9,11-dihydroxy-dodec-5-enoic acid methyl ester 
• 74581-57-0 (Z)-(R)-8-(tert-Butyl-diphenyl-silanyloxy)-8-((3aR,5S,6aR)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-oct-5-enoic acid methyl ester 
• 80126-58-5 methyl 8R-tert-butyldiphenylsilyloxy-11R-hydroxy-15-oxo-9S,12S-oxyeicosa-5Z,13E-dienoate 

Relevant academic research and scientific papers

Oxidation products of arachidonic acid I. The synthesis of methyl 8R, 11R, 15-trihydroxy-9S, 12-oxyeicosa-5Z, 13E-dienoate (19)

Diacetone glucose was converted in high yield to 3-deoxy-5-6-anhydro-1,2-0-isopropylidene-D-glucofuranose(3), which was transformed to title compound.3 Its mass spectrum confirms the structure of a naturally occurring oxidation product of arach