74597-04-9

Basic information

• Product Name: 3-(BROMOMETHYL)PHENOL
• Synonyms: 3-(BROMOMETHYL)PHENOL;AKOS 90890;3-Hydroxybenzylbromide;m-(Bromomethyl)phenol
• CAS NO: 74597-04-9
• Molecular Formula: C₇H₇BrO
• Molecular Weight: 187.03
• Mol File: 74597-04-9.mol
• Article Data: 25

Chemical Properties

• Boiling Point: 272℃
• Flash Point: 118℃
• Appearance: /
• Density: 1.593
• Vapor Pressure: 0.004mmHg at 25°C
• Refractive Index: 1.612
• Storage Temp.: Inert atmosphere,Store in freezer, under -20°C
• CAS DataBase Reference: 3-(BROMOMETHYL)PHENOL(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(BROMOMETHYL)PHENOL(74597-04-9)
• EPA Substance Registry System: 3-(BROMOMETHYL)PHENOL(74597-04-9)

Safety Data

• RIDADR: 2810
• HazardClass: 6.1
• PackingGroup: Ⅱ
• Hazardous Substances Data: 74597-04-9(Hazardous Substances Data)

Usage

Uses

3-?(Bromomethyl)?phenol is a reagent used in synthesis of furan-based heterocycles. Also used in the preparation of tetrahydroisoquinolinyl triazole carboxamide and triazole substituted benzamide analogues as σ2 receptors.

InChI:InChI=1/C7H7BrO/c8-5-6-2-1-3-7(9)4-6/h1-4,9H,5H2

Upstream product

• 19438-10-9 methyl 3-hydroxybenzoate 
• 100-83-4 meta-hydroxybenzaldehyde 
• 874-98-6 1-bromomethyl-3-methoxybenzene 
• 104-87-0 4-methyl-benzaldehyde 
• 620-24-6 3-Hydroxybenzyl alcohol 

Downstream Products

• 34708-66-2 Diaethyl-m-hydroxybenzylmalonat 
• 190442-16-1 3-hydroxy-α-nitrate-benzenemethanol 
• 873073-49-5 methyl 2(S)-2-[5-(bromomethyl)-2-chlorophenoxy]propionate 
• 108-39-4 3-methyl-phenol 
• 118469-71-9 2-(acetyloxy)-3-(hexadecyloxy)propyl 3-(bromomethyl)phenyl phosphoric acid ester 
• 117180-52-6 (+)-1-Oxa<2.2>metacyclophan 
• 115074-94-7 (-)-1-Oxa<2.2>metacyclophan 
• 106484-47-3 oxa<2.2>metacyclophane 
• 683215-21-6 2-(3-hydroxy-benzyl)-malonic acid 
• 646069-74-1 ((CH₃)3C)2PCH₂C₆H₄OP(CH(CH₃)2)2 
• 646069-73-0 (3-hydroxybenzyl)di-tert-butylphosphine 

Relevant articles and documents

A novel hydrosoluble near-infrared fluorescent probe for specifically monitoring tyrosinase and application in a mouse model

A novel hydrosoluble near-infrared (NIR) fluorescent probe that could specifically identify tyrosinase has been successfully constructed and applied for imaging of tyrosinase in living cells and zebrafish. Notably, the probe has been successfully applied to the diagnosis of melanoma in a xenogeneic mouse model.

Highly selective two-photon fluorescent off-on probes for imaging tyrosinase activity in living cells and tissues

A coumarin-based two-photon (TP) fluorescent off-on probe has been developed for detecting tyrosinase activity. High selectivity, sensitivity and biocompatibility enable the probes to successfully image tyrosinase activity in live cells and tissues using TP microscopy.

METHOD TO PREPARE PHENOLICS FROM BIOMASS

The present invention is directed to a method for preparing a final phenolic product from biomass comprising the steps of providing a furanic compound obtainable from biomass; reacting the furanic compound with a dienophile to obtain a phenolic compound; reacting the phenolic compound further to obtain the final phenolic product.