74607-57-1Relevant academic research and scientific papers
PHOSPHORORGANISCHE VERBINDUNGEN 93 Zur Chemie optisch aktiver Phosphinigsaereamide
Horner, Leopold,Jordan, Manfred
, p. 235 - 242 (2007/10/02)
Optically active ethyl-phenyl-phosphinous acid diethylamide 1 was treated with HCl, HBF4, alcohols, thiols, carboxylic acids, esters, anhydrides, acid chloride, compounds with the structure element P-Cl and secondary phosphines to give in each case a racemic mixture of the corresponding, previously described, reaction products.Reaction of optically active 1 with para-cresol, para-cresyltrifluoro-acetate or 2,2,2-trifluoro-ethyl-trifluoro-acetate gives the corresponding optically active ester of ethyl phenyl phosphinous acid under retention of configuration.
