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The Chemistry of Sulfur Diimides, 8. - Ene Reactions with Sulfur Diimides - Structure of the Ene Components and Reactivity in the Reaction with Ditosyl Sulfur Diimide
Bussas, Reinhard,Kresze, Guenter
, p. 629 - 649 (2007/10/02)
N,N'-Ditosyl sulfur diimide (1) is an exceptionally reactive enophilic compound.Its reactions with many allylic derivatives give sulfinamidines 3 or - by sigmatropic rearrangements of 3 - diamino sulfane derivatives 4, respectively, in good yields.Conclus
