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α-Nitro Ketones. 3. Stereochemistry of the Nitration of 1-Acetoxycyclohexenes: Synthesis of 2-Nitrocyclohexanones
Oezbal, Hadi,Zajac, Walter W.
, p. 3082 - 3087 (2007/10/02)
The nitration of enol acetates of substituted cyclohexanones in acetic anhydride at 15 deg C with concentrated nitric acid is a kinetically controlled process which can lead to cis-trans-substituted 2-nitrocyclohexanones in very good yields.The stereochem
