74609-73-7Relevant articles and documents
α-Nitro Ketones. 5. Synthesis of 2-Nitrocyclopentanones
Elfehail. Fadia E.,Zajac, Walter W.
, p. 5151 - 5155 (1981)
The synthesis of the trans-3-methyl-, trans-trans- and trans-cis-3,4-dimethyl-, trans-3,5,5-trimethyl-, and cis- and trans-5-methyl-2-nitrocyclopentanones was accomplished by nitration of substituted cyclopentanone enol acetates with nitric acid at 15 deg
α-Nitro Ketones. 3. Stereochemistry of the Nitration of 1-Acetoxycyclohexenes: Synthesis of 2-Nitrocyclohexanones
Oezbal, Hadi,Zajac, Walter W.
, p. 3082 - 3087 (2007/10/02)
The nitration of enol acetates of substituted cyclohexanones in acetic anhydride at 15 deg C with concentrated nitric acid is a kinetically controlled process which can lead to cis-trans-substituted 2-nitrocyclohexanones in very good yields.The stereochem