74609-82-8Relevant academic research and scientific papers
Nitration of 2-Cyclohexenone Derivatives and Some Reactions of the Products
Matoba, Katsuhide,Morita, Takashi,Yamazaki, Takao
, p. 4368 - 4375 (2007/10/02)
5,5-dimethyl-2-cyclohexenone (Ia) and isophorone (Ib) were nitrated with isoamyl nitrate using potassium metal in liquid ammonia to give 5,5-dimethyl-2-nitro-1,3-cyclohexadienol (III) and 3,5,5-trimethyl-2-nitro-2-cyclohexenone (IVb), respectively.Compoun
α-Nitro Ketones. 3. Stereochemistry of the Nitration of 1-Acetoxycyclohexenes: Synthesis of 2-Nitrocyclohexanones
Oezbal, Hadi,Zajac, Walter W.
, p. 3082 - 3087 (2007/10/02)
The nitration of enol acetates of substituted cyclohexanones in acetic anhydride at 15 deg C with concentrated nitric acid is a kinetically controlled process which can lead to cis-trans-substituted 2-nitrocyclohexanones in very good yields.The stereochem
