74632-44-3Relevant academic research and scientific papers
High Yields of Nitrene Insertion into Unactivated C-H Bonds. First Example of X-Ray Crystallographic and 19F NMR Analysis of the Photochemically Produced C-H Inserted Adduct
Pandurangi, Raghoottama S.,Katti, Kattesh V.,Barnes, Charles L.,Volkert, Wynn A.,Kuntz, Robert R.
, p. 1841 - 1842 (2007/10/02)
Photolysis of 4-azido-tetrafluorobenzonitrile results in the highest yield reported to date, (75 - 80percent as estimated from 19F NMR spectroscopy) for nitrene insertion into the unactivated C-H bond of cyclohexane; the photochemical adduct is characteri
SYNTHESIS AND PROPERTIES OF POLYFLUORINATED AROMATIC N,N-DICHLOROAMINES AND N-CHLOROIMINOPOLYFLUOROCHLORO-2,5-CYCLOHEXADIENES
Andreevskaya, O. I.,Markovskii, L. N.,Poleshchuk, O. Kh.,Furin, G. G.,Shermolovich, Yu. G.,Yakobson, G. G.
, p. 717 - 722 (2007/10/02)
The behaviour of 4-XC6F4NH2 (X=NO2, CN, F, H, CH3, OCH3, C4H9) in reaction with tert-butyl hypochlorite was investigated.Polyfluorinated anilines containing electron-donating substituents form N-chloroiminopolyfluorochloro-2,5-cyclohexadienes, whereas the
