74641-45-5Relevant academic research and scientific papers
PHOTOREAKTIONEN DES 3-(2-THIENYL)-2,2-DIMETHYL-2H-AZIRINS
Pfoertner, Karl-Heinz
, p. 645 - 652 (1980)
The synthesis of 3-(2-thienyl)-2,2-dimethyl-2H-azirine (1) is described.UV. irradiation of 1 in benzene solution generates the nitrile isoprpylide 2 which reacts in a regiospecific manner with activated C,C and C,O double bonds to give 1-pyrrolines and 3-oxazolines, respectively.With chelidonic acid diethyl ester the cycloaddition of 2 to the C,C double bond is preferred.
