74653-53-5Relevant articles and documents
Formation and Characterization of (Dimethylamido)dithiomethylphosphonic Acid and its Salts
Seel, Fritz,Zindler, Guenter
, p. 1837 - 1846 (2007/10/02)
The title compound 3, which exhibits a betaine-like structure, and its metal derivatives (Cu, Ag, Tl)L, (Co, Ni, Zn, Cd)L2, NiL2*2Py, and CoL3 (L = anion of 3) have been obtained from the dimethylammonium salt 2, which is readily accessible from 3 and dimethylamine.The crystal structure of NiL2 (9) was solved with X-ray diffraction data.In an aqueous solution, 2 is oxidised by iodine to give the sulfane derivative 21.Hydrogen sulfide, hydrogen selenide and methylmercaptan readily substitute the dimethylamino group of 2 to yield the dimethylammonium salts 22, 23, 24 of trithio-, dithioseleno-, and methyl trithiomethylphosphonic acids.