746595-79-9Relevant academic research and scientific papers
Preparation process of oxygen dinitrogen heterocyclic compound
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Paragraph 0030-0055, (2020/10/14)
The invention discloses a preparation process of an oxygen dinitrogen heterocyclic compound, and belongs to the technical field of synthesis of nitrogen-oxygen heterocyclic compounds. The preparationprocess comprises the following steps: reacting a N-substituent carbonyl oxygen dinitrogen heterocyclic compound with hydrogen in a non-polar solvent or a polar solvent under the action of a catalystto obtain the oxygen dinitrogen heterocyclic compound. The process is mild in reaction conditions; the reaction system is green and environment-friendly, the reaction byproducts are toluene and gaseous carbon dioxide, which do not influence subsequent reactions, no waste gas, waste solid, or wastewater is generated, the product yield is high, the reaction solution of the obtained product can be directly used for subsequent synthesis of pinoxaden only by filtration, the catalyst can be recycled, and the preparation process is high in safety, low in cost, high in process adaptability, wide in application range and suitable for industrial production.
Preparation process and application of oxygen dinitrogen heterocyclic compound
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Paragraph 0053; 0054, (2018/07/30)
The invention provides a preparation process and application of an oxygen dinitrogen heterocyclic compound. The preparation process includes: enabling N-carbalkoxy hydrazine and disubstituted ether tobe in cyclization reaction under action of alkali to obtain a N-carbalkoxy oxygen dinitrogen heterocyclic compound; enabling the N-carbalkoxy oxygen dinitrogen heterocyclic compound to be in deprotection reaction with the alkali to obtain the oxygen dinitrogen heterocyclic compound. A new N-protection strategy is used, so that consumption of expensive protection agents is avoided, and reaction yield is increased. In addition, the preparation process has the advantages that three wastes are few, operation is simple and equipment is less prone to corrosion, and is conducive to industrial production.
Preparation process and application of dinitrogen oxide heterocyclic compound
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Paragraph 0025; 0027; 0029; 0031; 0034; 0035, (2018/07/30)
The invention relates to a preparation process and application of a dinitrogen oxide heterocyclic compound. The preparation process is characterized in that a N,N-diacyl dinitrogen oxide heterocycliccompound is used as the raw material, the N,N-diacyl dinitrogen oxide heterocyclic compound is allowed to have reaction with alkali in a nonpolar solvent to obtain the dinitrogen oxide heterocyclic compound, and the dinitrogen oxide heterocyclic compound is subjected to further reaction to be converted into herbicides such as pinoxaden. Compared with the prior art, the preparation process is highin yield, convenient to operate, little in waste gas, wastewater and solid waste and beneficial to industrial production.
A PROCESS FOR THE PREPARATION OF [1,4,5]-OXADIAZEPINE DERIVATIVES
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Page/Page column 6, (2008/06/13)
A process for the preparation of [1,4,5]-oxidiazepine derivatives by reaction of 4,5-diacyl-[1,4,5]-oxidiazepines with a base.
