746621-69-2

Basic information

• Product Name: 4H-1-Benzopyran-4-one, 3-(4-methoxy-2-nitrophenyl)-7-[2-(1-piperidinyl)ethoxy]-
• CAS NO: 746621-69-2
• Molecular Formula: C23H24N2O6
• Molecular Weight: 424.453
• Mol File: 746621-69-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4H-1-Benzopyran-4-one, 3-(4-methoxy-2-nitrophenyl)-7-[2-(1-piperidinyl)ethoxy]-(CAS DataBase Reference)
• NIST Chemistry Reference: 4H-1-Benzopyran-4-one, 3-(4-methoxy-2-nitrophenyl)-7-[2-(1-piperidinyl)ethoxy]-(746621-69-2)
• EPA Substance Registry System: 4H-1-Benzopyran-4-one, 3-(4-methoxy-2-nitrophenyl)-7-[2-(1-piperidinyl)ethoxy]-(746621-69-2)

Safety Data

• Hazardous Substances Data: 746621-69-2(Hazardous Substances Data)

Upstream product

• 332150-57-9 1-(2,4-dihydroxy-phenyl)-2-(4-methoxy-2-nitro-phenyl)-ethanone 
• 20876-30-6 (4-methoxy-2-nitro-phenyl)-acetic acid 
• 2008-75-5 N-chloroethylpiperidine hydrochloride 
• 332150-59-1 7-hydroxy-3-(4-methoxy-2-nitro-phenyl)-chromen-4-one 
• 10298-80-3 2-chloro-5-methoxynitrobenzene 
• 105003-90-5 (4-methoxy-2-nitro-phenyl)-acetonitrile 

Relevant articles and documents

An aminoisoflavone-salicyloylindole ring transformation

A series of 2′-nitroisoflavones 8-10, 15, 22, 27 and 28 was prepared via the (2-nitro-phenyl)-acetic acids 1, 13, 19 and 25. In order to obtain the corresponding 2′-aminoisoflavones the reduction of 8-10, 15, 22, 27 and 28 was undertaken. Surprisingly, new 3-salicyloylindoles instead of the expected 2′-aminoisoflavones were the main reduction products. In the following paper the preparation of the 2′-nitroisoflavones 8-10, 15, 22, 27 and 28 as well as the reduction experiments obtaining the 2′-aminoisoflavones 33 and 35 and the 3-salicyloylindoles 29-32, 34 and 36 will be described. Furthermore, a possible mechanism responsible for the formation of the 3-salicyloylindoles from 2′-nitroisoflavones under reductive conditions will be discussed.