746651-80-9Relevant academic research and scientific papers
Iron-Catalyzed Acylation of Polyfunctionalized Aryl- and Benzylzinc Halides with Acid Chlorides
Benischke, Andreas D.,Leroux, Marcel,Knoll, Irina,Knochel, Paul
supporting information, p. 3626 - 3629 (2016/08/16)
FeCl2 (5 mol %) catalyzes a smooth and convenient acylation of functionalized arylzinc halides at 50 °C (2-4 h) and benzylic zinc chlorides at 25 °C (0.5-4 h) with a variety of acid chlorides leading to polyfunctionalized diaryl and aryl heteroaryl ketones.
Air-stable solid aryl and heteroaryl organozinc pivalates: Syntheses and applications in organic synthesis
Manolikakes, Sophia M.,Ellwart, Mario,Stathakis, Christos I.,Knochel, Paul
, p. 12289 - 12297 (2015/03/31)
A wide range of air-stable, solid, polyfunctional aryl and heteroarylzinc pivalates were efficiently prepared by either magnesium insertion or Hal/Mg exchange followed by transmetalation with Zn(OPiv)2 (OPiv=pivalate). By reducing the amount of
