746677-17-8

Basic information

• Product Name: [IrCl(H)(P(CH(CH₃)2)3)2(CHC(C₆H₅)C(O)C(CH₃)CHC₂H₅)]
• CAS NO: 746677-17-8
• Molecular Weight: 748.432
• Mol File: 746677-17-8.mol

Chemical Properties

• CAS DataBase Reference: [IrCl(H)(P(CH(CH₃)2)3)2(CHC(C₆H₅)C(O)C(CH₃)CHC₂H₅)](CAS DataBase Reference)
• NIST Chemistry Reference: [IrCl(H)(P(CH(CH₃)2)3)2(CHC(C₆H₅)C(O)C(CH₃)CHC₂H₅)](746677-17-8)
• EPA Substance Registry System: [IrCl(H)(P(CH(CH₃)2)3)2(CHC(C₆H₅)C(O)C(CH₃)CHC₂H₅)](746677-17-8)

Safety Data

• Hazardous Substances Data: 746677-17-8(Hazardous Substances Data)

Upstream product

• 188261-90-7 [IrCl(P(CH(CH₃)2)3)2(CH₃CCC₂H₅)] 
• 3156-07-8 methyl phenyl ketene 

Relevant articles and documents

Double C-H activation during functionalization of phenyl(methyl)ketene on iridium(I) using alkynes. Synthesis of 1,4-dien-3-ones

Under the influence of an Ir(I) metal fragment, the methyl group of phenyl(methyl)ketene undergoes two C-H activations in reacting with internal alkynes, giving metallacycles 3 in 86-94% yield. Treatment of 3 with CO liberates 1,4-dien-3-ones 5 in 81-93% yield, along with CO complex 4. A possible mechanism for the very selective double C-H activation-alkyne coupling is discussed. Copyright