74670-77-2Relevant academic research and scientific papers
On the thermal Pummerer rearrangement of substituted sulfoxides
Marzorati, Liliana,Yoshikawa, Eduardo K.C.,Braga, Ataualpa A.C.,Di Vitta, Claudio
, p. 248 - 260 (2014/04/03)
Sulfoxides bearing thioester and ester groups at the position under heating at ca. 140C undergo Pummerer thermal rearrangement. However, for sulfonyl sulfoxide, a complex mixture of products is formed. Plausible mechanism is advanced(equation presented. 2013
