74684-34-7Relevant academic research and scientific papers
The quest for a better understanding of ethanol coordination to magnesium and zinc porphyrin: A combined experimental and theoretical study
Borah, Bishnu Prasad,Majumder, Smita,Borah, Karishma Devi,Bhuyan, Jagannath
, (2021)
An ethanol coordinated magnesium porphyrin [Mg(TDMPP)(C2H5OH)], (TDMPP = 5,10,15,20-tetrakis(3,5-dimethoxyphenyl)porphyrin), 1 was synthesized and characterized by single crystal X-ray diffraction method along with other standard spe
Triplet state spectroscopic studies on some 5,10,15,20-tetrakis(methoxyphenyl)porphyrins
Katona,Grofcsik,Baranyai,Bitter,Grabner,Kubinyi,Vidoczy
, p. 41 - 45 (1998)
Extensive triplet state spectroscopic investigations were carried out with a series of 5,10,15,20-tetrakis(methoxyphenyl)porphyrins. Triplet absorption spectra, triplet lifetime, triplet quantum yield and quantum yield for singlet oxygen production were d
Preparation method of substituted aryl porphyrin
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Paragraph 0058-0061, (2019/07/04)
The invention provides a preparation method of substituted aryl porphyrin. The method comprises the following steps that a, aromatic aldehyde shown in the formula (1) is dissolved in a reaction solvent to obtain a dissolving solution; b, pyrrole is dropwi
Design of two-photon absorbing fluorophores for FRET antenna-core oxygen probes
Zheng, Zheng,Ayhan, Mehmet Menaf,Liao, Yuan-Yuan,Calin, Nathalie,Bucher, Christophe,Andraud, Chantal,Bretonnière, Yann
, p. 7914 - 7930 (2018/05/24)
Four two-photon absorbing fluorophores A1-A4 are reported and their spectroscopic properties are analyzed for use, in combination with palladium-porphyrinato complexes C1 and C2, as two-photon absorbing antennas and energy donors for FRET-based antenna-co
Ni(II) complex of octasubstituted tetraphenylporphine as a stationary phase for gas chromatography
Burmistrov, Vladimir A.,Semeikin, Alexander S.,Kuvshinov, Gregory V.,Aleksandriiskii, Victor V.,Lubimova, Tatiana V.,Kuvshinova, Sofia A.,Koifman, Oscar I.
, p. 103 - 109 (2017/04/24)
The Ni(II) complex of 5,10,15,20-Tetrakis[3′,5′-di(2′′-methylbutyloxy)phenyl]porphine was synthesized and characterized by 1H NMR, UV-vis spectroscopy and MALDI-TOF mass-spectrometry. The stationary phase on the base of synthesized Ni(II) complex was used for chromatographic separation of isomeric methyl-And dimethylpyridines. The high structural selectivity of this sorbent was explained by giving the results of DFT calculation of pyridine derivatives axial complexes with porphyrin Ni(II) complexes.
New highly brominated Mn-porphyrin: A good catalyst for activation of inert C-H bonds
Santos Da Silva, Vinicius,Nakagaki, Shirley,Ucoski, Geani Maria,Idemori, Ynara Marina,DeFreitas-Silva, Gilson
, p. 106589 - 106598 (2016/01/08)
This work describes the synthesis and characterization of a novel third-generation catalyst 5,10,15,20-tetrakis-(4′-bromine-3′,5′-dimethoxyphenyl)-2,3,7,8,12,13,17,18-octabromoporphyrinatomanganese chloride [MnIIIBr12T3,5DMPP]Cl (Cat.2). The catalytic activity of Cat.2 in cyclohexane, adamantane, and n-hexane oxidation by iodosylbenzene (PhIO) or iodobenzene diacetate (PhI(OAc)2) was compared with the catalytic activity of [MnIIIT3,5DMPP]Cl (Cat.1), a second generation catalyst. The Cat.2/PhI(OAc)2 system led to higher yields of cyclohexane oxidation products (65%) with high selectivity for cyclohexanol (86%) as compared with Cat.1 (19% and 74%, respectively) and addition of water essentially did not alter total product yield. Addition of a small amount of imidazole to the Cat.1/PhIO system gave superior yields of cyclohexane oxidation products (64%) as compared with Cat.2 (52%). In all systems Cat.2 afforded significantly higher yields of 2-adamantanol, a product with great commercial value compared with 1-adamantanol. n-Hexane oxidation gave low total product yield; Cat.2 was more selective for alcohol products (2-hexanol and 3-hexanol).
High-Boron-Content Porphyrin-Cored Aryl Ether Dendrimers: Controlled Synthesis, Characterization, and Photophysical Properties
Cabrera-González, Justo,Xochitiotzi-Flores, Elba,Vi?as, Clara,Teixidor, Francesc,García-Ortega, Héctor,Farfán, Norberto,Santillan, Rosa,Parella, Teodor,Nú?ez, Rosario
supporting information, p. 5021 - 5031 (2015/05/27)
The synthesis and characterization of a set of poly(aryl ether) dendrimers with tetraphenylporphyrin as the core and 4, 8, 16, or 32 closo-carborane clusters are described. A regioselective hydrosilylation reaction on the allyl-terminated functions with c
Broad hexagonal columnar mesophases formation in bioinspired transition-metal complexes of simple fatty acid meta-octaester derivatives of meso-tetraphenyl porphyrins
Wu, Bin,Chen, Keyang,Deng, Yuchen,Chen, Jian,Liu, Chengjie,Cheng, Rongshi,Chen, Dongzhong
, p. 3671 - 3681 (2015/03/04)
A series of meta-substituted fatty acid octaester derivatives and their transition-metal complexes of mesotetraphenyl porphyrins (TPP-8OOCR, with R = Cn-1H2n-1, n = 8, 12, or 16) have been prepared through very simple synthesis proto
Synthesis and investigation of singlet oxygen production efficiency of photosensitizers based on meso-phenyl-2,5-thienylene linked porphyrin oligomers and polymers
Khan, Rehan,Idris, Muazzam,Tuncel, D?nüs
, p. 10496 - 10504 (2015/11/10)
Three new Zn(ii)-, oligo- and poly(2,5-thienylene)-linked porphyrins, bearing multiple triethylene glycol (TEG) groups, on all meso aryl positions were synthesized via Stille and Suzuki coupling reactions and their photophysical properties as well as singlet oxygen generation efficiencies have been investigated to elucidate the possibility of their use as a photosensitizer for photodynamic therapy (PDT) and photodynamic inactivation of bacteria.
Convenient synthetic route of versatile 21-monothiatetraphenylporphyrins of the A4 and AB3 type
Stute, Silvio,Gloe, Kerstin,Gloe, Karsten
, p. 2907 - 2912 (2007/10/03)
A novel convenient synthetic route for poly-functional 21- monothiatetraphenylporphyrins of the type A4 und AB3 having base labile substituents in meso position was developed. Using this method a series of symmetric and asymmetric 21-thiaporphyrins containing different functional groups at the meso position is reported. The new products were characterized by NMR, UV-Vis and mass spectroscopy.
