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5,10,15,20-TETRAKIS(3,5-DIMETHOXYPHENYL)-21H,23H-PORPHINE, commonly referred to as TDMPP, is a synthetic porphyrin characterized by its unique light absorption and emission properties. This tetrakis-substituted porphine features four 3,5-dimethoxyphenyl groups attached to its porphine core, which significantly enhances its solubility. TDMPP's distinctive attributes make it a valuable compound for various applications, particularly in the fields of medicine and solar energy conversion.

74684-34-7

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74684-34-7 Usage

Uses

Used in Photodynamic Therapy:
5,10,15,20-TETRAKIS(3,5-DIMETHOXYPHENYL)-21H,23H-PORPHINE is used as a photosensitizer in photodynamic therapy for its ability to absorb light and generate reactive oxygen species, which can effectively target and destroy cancer cells while minimizing damage to surrounding healthy tissues.
Used in Solar Energy Conversion:
In the field of solar energy, 5,10,15,20-TETRAKIS(3,5-DIMETHOXYPHENYL)-21H,23H-PORPHINE is utilized as a light-harvesting molecule due to its strong light absorption capabilities, contributing to the efficiency of solar cells and other energy conversion devices.
Used in Research and Development:
5,10,15,20-TETRAKIS(3,5-DIMETHOXYPHENYL)-21H,23H-PORPHINE is employed as a key component in the development of new photonic materials and light-driven systems, given its enhanced solubility and light-handling properties, which facilitate the creation of innovative applications in various industries.
Used in the Pharmaceutical Industry:
In the pharmaceutical sector, 5,10,15,20-TETRAKIS(3,5-DIMETHOXYPHENYL)-21H,23H-PORPHINE is used as a building block for the synthesis of novel drugs and drug delivery systems, capitalizing on its light-sensitive nature to develop targeted therapies and improve drug efficacy.
Used in the Chemical Industry:
5,10,15,20-TETRAKIS(3,5-DIMETHOXYPHENYL)-21H,23H-PORPHINE is utilized as a functional dye or pigment in various chemical applications, taking advantage of its light absorption and emission characteristics to create specialized products with unique optical properties.

Check Digit Verification of cas no

The CAS Registry Mumber 74684-34-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 7,4,6,8 and 4 respectively; the second part has 2 digits, 3 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 74684-34:
(7*7)+(6*4)+(5*6)+(4*8)+(3*4)+(2*3)+(1*4)=157
157 % 10 = 7
So 74684-34-7 is a valid CAS Registry Number.
InChI:InChI=1/C52H46N4O8/c1-57-33-17-29(18-34(25-33)58-2)49-41-9-11-43(53-41)50(30-19-35(59-3)26-36(20-30)60-4)45-13-15-47(55-45)52(32-23-39(63-7)28-40(24-32)64-8)48-16-14-46(56-48)51(44-12-10-42(49)54-44)31-21-37(61-5)27-38(22-31)62-6/h9-28,53,56H,1-8H3/b49-41-,49-42-,50-43-,50-45-,51-44-,51-46-,52-47-,52-48-

74684-34-7 Well-known Company Product Price

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  • TCI America

  • (T1832)  5,10,15,20-Tetrakis(3,5-dimethoxyphenyl)porphyrin  >95.0%(HPLC)

  • 74684-34-7

  • 100mg

  • 990.00CNY

  • Detail

74684-34-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name 5,10,15,20-Tetrakis(3,5-Dimethoxyphenyl)-21H,23H-Porphine

1.2 Other means of identification

Product number -
Other names 5,10,15,20-tetrakis(3,5-dimethoxyphenyl)-21,22-dihydroporphyrin

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:74684-34-7 SDS

74684-34-7Relevant academic research and scientific papers

The quest for a better understanding of ethanol coordination to magnesium and zinc porphyrin: A combined experimental and theoretical study

Borah, Bishnu Prasad,Majumder, Smita,Borah, Karishma Devi,Bhuyan, Jagannath

, (2021)

An ethanol coordinated magnesium porphyrin [Mg(TDMPP)(C2H5OH)], (TDMPP = 5,10,15,20-tetrakis(3,5-dimethoxyphenyl)porphyrin), 1 was synthesized and characterized by single crystal X-ray diffraction method along with other standard spe

Triplet state spectroscopic studies on some 5,10,15,20-tetrakis(methoxyphenyl)porphyrins

Katona,Grofcsik,Baranyai,Bitter,Grabner,Kubinyi,Vidoczy

, p. 41 - 45 (1998)

Extensive triplet state spectroscopic investigations were carried out with a series of 5,10,15,20-tetrakis(methoxyphenyl)porphyrins. Triplet absorption spectra, triplet lifetime, triplet quantum yield and quantum yield for singlet oxygen production were d

Preparation method of substituted aryl porphyrin

-

Paragraph 0058-0061, (2019/07/04)

The invention provides a preparation method of substituted aryl porphyrin. The method comprises the following steps that a, aromatic aldehyde shown in the formula (1) is dissolved in a reaction solvent to obtain a dissolving solution; b, pyrrole is dropwi

Design of two-photon absorbing fluorophores for FRET antenna-core oxygen probes

Zheng, Zheng,Ayhan, Mehmet Menaf,Liao, Yuan-Yuan,Calin, Nathalie,Bucher, Christophe,Andraud, Chantal,Bretonnière, Yann

, p. 7914 - 7930 (2018/05/24)

Four two-photon absorbing fluorophores A1-A4 are reported and their spectroscopic properties are analyzed for use, in combination with palladium-porphyrinato complexes C1 and C2, as two-photon absorbing antennas and energy donors for FRET-based antenna-co

Ni(II) complex of octasubstituted tetraphenylporphine as a stationary phase for gas chromatography

Burmistrov, Vladimir A.,Semeikin, Alexander S.,Kuvshinov, Gregory V.,Aleksandriiskii, Victor V.,Lubimova, Tatiana V.,Kuvshinova, Sofia A.,Koifman, Oscar I.

, p. 103 - 109 (2017/04/24)

The Ni(II) complex of 5,10,15,20-Tetrakis[3′,5′-di(2′′-methylbutyloxy)phenyl]porphine was synthesized and characterized by 1H NMR, UV-vis spectroscopy and MALDI-TOF mass-spectrometry. The stationary phase on the base of synthesized Ni(II) complex was used for chromatographic separation of isomeric methyl-And dimethylpyridines. The high structural selectivity of this sorbent was explained by giving the results of DFT calculation of pyridine derivatives axial complexes with porphyrin Ni(II) complexes.

New highly brominated Mn-porphyrin: A good catalyst for activation of inert C-H bonds

Santos Da Silva, Vinicius,Nakagaki, Shirley,Ucoski, Geani Maria,Idemori, Ynara Marina,DeFreitas-Silva, Gilson

, p. 106589 - 106598 (2016/01/08)

This work describes the synthesis and characterization of a novel third-generation catalyst 5,10,15,20-tetrakis-(4′-bromine-3′,5′-dimethoxyphenyl)-2,3,7,8,12,13,17,18-octabromoporphyrinatomanganese chloride [MnIIIBr12T3,5DMPP]Cl (Cat.2). The catalytic activity of Cat.2 in cyclohexane, adamantane, and n-hexane oxidation by iodosylbenzene (PhIO) or iodobenzene diacetate (PhI(OAc)2) was compared with the catalytic activity of [MnIIIT3,5DMPP]Cl (Cat.1), a second generation catalyst. The Cat.2/PhI(OAc)2 system led to higher yields of cyclohexane oxidation products (65%) with high selectivity for cyclohexanol (86%) as compared with Cat.1 (19% and 74%, respectively) and addition of water essentially did not alter total product yield. Addition of a small amount of imidazole to the Cat.1/PhIO system gave superior yields of cyclohexane oxidation products (64%) as compared with Cat.2 (52%). In all systems Cat.2 afforded significantly higher yields of 2-adamantanol, a product with great commercial value compared with 1-adamantanol. n-Hexane oxidation gave low total product yield; Cat.2 was more selective for alcohol products (2-hexanol and 3-hexanol).

High-Boron-Content Porphyrin-Cored Aryl Ether Dendrimers: Controlled Synthesis, Characterization, and Photophysical Properties

Cabrera-González, Justo,Xochitiotzi-Flores, Elba,Vi?as, Clara,Teixidor, Francesc,García-Ortega, Héctor,Farfán, Norberto,Santillan, Rosa,Parella, Teodor,Nú?ez, Rosario

supporting information, p. 5021 - 5031 (2015/05/27)

The synthesis and characterization of a set of poly(aryl ether) dendrimers with tetraphenylporphyrin as the core and 4, 8, 16, or 32 closo-carborane clusters are described. A regioselective hydrosilylation reaction on the allyl-terminated functions with c

Broad hexagonal columnar mesophases formation in bioinspired transition-metal complexes of simple fatty acid meta-octaester derivatives of meso-tetraphenyl porphyrins

Wu, Bin,Chen, Keyang,Deng, Yuchen,Chen, Jian,Liu, Chengjie,Cheng, Rongshi,Chen, Dongzhong

, p. 3671 - 3681 (2015/03/04)

A series of meta-substituted fatty acid octaester derivatives and their transition-metal complexes of mesotetraphenyl porphyrins (TPP-8OOCR, with R = Cn-1H2n-1, n = 8, 12, or 16) have been prepared through very simple synthesis proto

Synthesis and investigation of singlet oxygen production efficiency of photosensitizers based on meso-phenyl-2,5-thienylene linked porphyrin oligomers and polymers

Khan, Rehan,Idris, Muazzam,Tuncel, D?nüs

, p. 10496 - 10504 (2015/11/10)

Three new Zn(ii)-, oligo- and poly(2,5-thienylene)-linked porphyrins, bearing multiple triethylene glycol (TEG) groups, on all meso aryl positions were synthesized via Stille and Suzuki coupling reactions and their photophysical properties as well as singlet oxygen generation efficiencies have been investigated to elucidate the possibility of their use as a photosensitizer for photodynamic therapy (PDT) and photodynamic inactivation of bacteria.

Convenient synthetic route of versatile 21-monothiatetraphenylporphyrins of the A4 and AB3 type

Stute, Silvio,Gloe, Kerstin,Gloe, Karsten

, p. 2907 - 2912 (2007/10/03)

A novel convenient synthetic route for poly-functional 21- monothiatetraphenylporphyrins of the type A4 und AB3 having base labile substituents in meso position was developed. Using this method a series of symmetric and asymmetric 21-thiaporphyrins containing different functional groups at the meso position is reported. The new products were characterized by NMR, UV-Vis and mass spectroscopy.

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