74714-03-7Relevant academic research and scientific papers
SELECTIVE MONO-ALKYLATION AND ARYLATION OF AROMATIC DIHALIDES BY PALLADIUM-CATALYZED CROSS-COUPLING WITH THE GRIGNARD AND ORGANOZINC REAGENTS
Minato, Akio,Tamao, Kohei,Hayashi, Tamio,Suzuki, Keizo,Kumada, Makoto
, p. 845 - 848 (1980)
Dibromobenzene, dibromothiophenes, dichloro- and dibromopyridine are highly selectively mono-alkylated and arylated with Grignard or organozinc reagents in the presence of palladium complexes as catalysts.
SYNTHESIS OF A LIGNAN SKELETON VIA NICKEL- AND PALLADIUM-PHOSPHINE COMPLEX CATALYZED GRINGARD COUPLING REACTION OF HALOTHIOPHENES
Minato, Akio,Tamao, Kohei,Suzuki, Keizo,Makoto, Kumada
, p. 4017 - 4020 (2007/10/02)
A lignan skeleton is prepared in good yield through desulfurization of 3,4-dibenzylthiophene or 2,5-diaryl-3,4-dimethylthiophenes which are obtained by nickel- or palladium-phosphine complex catalyzed Gringard cross-coupling reaction of halothiophenes.
