74743-93-4

Basic information

• Product Name: 5-amino-2-hexenedioic acid
• Synonyms: 5-amino-2-hexenedioic acid
• CAS NO: 74743-93-4
• Molecular Formula: C6H9 N O4
• Molecular Weight: 0
• Mol File: 74743-93-4.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 423.5°C at 760 mmHg
• Flash Point: 209.9°C
• Appearance: /
• Density: 1.389g/cm³
• Vapor Pressure: 2.34E-08mmHg at 25°C
• Refractive Index: 1.55
• CAS DataBase Reference: 5-amino-2-hexenedioic acid(CAS DataBase Reference)
• NIST Chemistry Reference: 5-amino-2-hexenedioic acid(74743-93-4)
• EPA Substance Registry System: 5-amino-2-hexenedioic acid(74743-93-4)

Safety Data

• Hazardous Substances Data: 74743-93-4(Hazardous Substances Data)

Usage

InChI:InChI=1/C6H9NO4/c7-4(6(10)11)2-1-3-5(8)9/h1,3-4H,2,7H2,(H,8,9)(H,10,11)/b3-1+

Upstream product

• 121704-22-1 (E)-5-(2-Chloro-acetylamino)-hex-2-enedioic acid 

Downstream Products

• 1118-90-7 L-homoglutamic acid 

Relevant articles and documents

Synthesis of hexahydroindole carboxylic acids by intramolecular Diels-Alder reaction

By applying an intramolecular Diels-Alder reaction highly functionalized Δ6,7-hexahydroindoles were prepared in good yields. Georg Thieme Verlag Stuttgart.

Synthesis of (R)-5-Aminohex-2-enedioic acid and the (+/-)-2-Bromo Derivative as Unsaturated Analogues of the Neurotransmitter Antagonist D-&α-Aminoadipic Acid

5-Aminohex-2-enedioic acid (2), an unsaturated analogue of the neurotransmitter antagonist D-α-aminoadipic acid, has been synthesised by a convenient route using a phase-transfer alkylation of N-diphenylmethyleneglycine ethyl ester.The unsaturated amino acid has been resolved and the absolute stereochemistry of the (-) isomer determined as R by reduction to D-α-aminoadipic acid.A more conventional synthetic scheme failed to yield (2), but led to the preparation of the (+/-)-2-bromo derivative (4) in low yield.