74753-27-8Relevant academic research and scientific papers
The solution structure and fluxional behaviour of cyclic and acyclic (diene)Fe(CO)2L complexes (L = phosphine, phosphite, isonitrile)
Howell, James A. S.,Walton, Gary,Tirvengadum, Marie-Claire,Squibb, Adrian D.,Palin, Michael G.,et al.
, p. 91 - 123 (2007/10/02)
Variable temperature 13C and 31P NMR spectroscopy has been used to establish solution structures and conformer populations for a variety of cyclic and acyclic (diene)Fe(CO)2L complexes (L = phosphine, phosphite, isonitrile).The solid state structures of (2,3-dimethylbutadiene)Fe(CO)2PPh3 and (trans,trans-2,4-hexadiene)Fe(CO)2PPh3 have been determined and used as a basis for molecular modelling of steric effects in these complexes.
(Diene)Fe(CO)PR3 and X complexes: altered reactivity towards electrophiles and nucleophiles
Howell, James A. S.,Tirvengadum, Marie-Claire,Walton, Garry
, p. 217 - 222 (2007/10/02)
Substitution of carbonyl by PPh3 in (diene)Fe(CO)3 complexes changes the regiospecificity of electrophilic attack and provides easier acces to X salts.Similar PPh3 substitution in X complexes results in decreased reactivity t
Photolytic cleavage and isomerization reactions of (1-σ,4-6-η3-organo)tricarbonyliron complexes involving an (η4-diene)(η2-olefin)Fe(CO)2 intermediate. Quantum yields and mechanistic studies
Akiyama, Takeo,Grevels, Friedrich-Wilhelm,Reuvers, Johannes G. A.,Ritterskamp, Peter
, p. 157 - 160 (2008/10/08)
Photolysis of two isomeric (1-σ,4-6-η3-organo)Fe(CO)3 complexes (1a/1b) - the organic moiety being an adduct of methyl acrylate and 2,3-dimethylbutadiene-results in the interconversion of the two isomers and in the cleavage of the in
