74758-69-3Relevant academic research and scientific papers
Synthesis of 1,1-Bis(seleno)-2-alkenes
Dieden, R.,Hevesi, L.
, p. 616 - 619 (2007/10/02)
The success of the direct conversion of α,β-unsaturated carbonyl compounds into the corresponding diselenoacetals by means of selenol/zinc chloride or tris(seleno)borane greatly depends on the starting carbonyl derivative.Enals and cyclic enones are transformed most efficiently, whereas acyclic enones mainly produce 1,4-addition compounds.
A DIRECT ARYLSELENENYLATION OF ENONES WITH DIARYL DISELENIDES BY A ELECTROREDUCTIVE PROCEDURE
Torii, Sigeru,Inokuchi, Tsutomu,Hasegawa, Nobu
, p. 639 - 640 (2007/10/02)
A new procedure for arylselenenylation of enones has been developed by electrolysis with diaryl diselenide and chlorotrimethylsilane in methanol.In the course of the reaction generation of aryl selenols in situ is assumed.
