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di-(1-pyrenylmethyl)ether is a hydrophobic fluorescent probe that exhibits intramolecular excimer fluorescence (intensity IE) in competition with fluorescence from the locally excited pyrene chromophore (monomer emission, intensity IM). It is characterized by its ability to investigate the fluidity and micropolarity of polymeric micelles in aqueous solutions of copolymers, making it a valuable tool for studying hydrophobic microenvironments.

74833-81-1

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74833-81-1 Usage

Uses

Used in Polymer Science:
di-(1-pyrenylmethyl)ether is used as a fluorescent probe for investigating the fluidity and micropolarity of polymeric micelles in aqueous solutions of copolymers, such as N-isopropylacrylamide and other acrylamides. This application is crucial for understanding the behavior and properties of these micelles, which can be important in various fields, including drug delivery and materials science.
Used in Analytical Chemistry:
di-(1-pyrenylmethyl)ether serves as a valuable tool for studying hydrophobic microenvironments, which can be essential for analyzing and characterizing the properties of various compounds and materials. Its ability to provide insights into the fluidity and micropolarity of polymeric micelles makes it a useful instrument in the field of analytical chemistry.

Check Digit Verification of cas no

The CAS Registry Mumber 74833-81-1 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 7,4,8,3 and 3 respectively; the second part has 2 digits, 8 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 74833-81:
(7*7)+(6*4)+(5*8)+(4*3)+(3*3)+(2*8)+(1*1)=151
151 % 10 = 1
So 74833-81-1 is a valid CAS Registry Number.

74833-81-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name 1-(pyren-1-ylmethoxymethyl)pyrene

1.2 Other means of identification

Product number -
Other names DPYME

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:74833-81-1 SDS

74833-81-1Downstream Products

74833-81-1Relevant academic research and scientific papers

Borrowing hydrogen: Indirect "Wittig" olefination for the formation of C-C bonds from alcohols

Black, Phillip J.,Edwards, Michael G.,Williams, Jonathan M. J.

, p. 4367 - 4378 (2006)

The successful development of an indirect three-step domino sequence for the formation of C-C bonds from alcohol substrates is described. An iridium-catalysed dehydrogenation of alcohol 1 affords the intermediate aldehyde 2. The desired C-C bond can then be formed by a facile Wittig olefination, yielding the intermediate alkene 3. In the final step the alkene is hydrogenated to afford the indirect Wittig product, the alkane 4. The key to this process is the concept of borrowing hydrogen; hydrogen removed in the initial dehydrogenation step is simply borrowed by the iridium catalyst. Functioning as a hydrogen reservoir, the catalyst facilitates C-C bond formation before subsequently returning the borrowed hydrogen in the final step. Herein we present full details of our examination into both the substrate and reaction scope and the limitations of the catalytic cycle. Wiley-VCH Verlag GmbH & Co. KGaA, 2006.

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