74866-17-4Relevant articles and documents
Pd-Catalyzed Nazarov-Type Cyclization: Application in the Total Synthesis of β-Diasarone and Other Complex Cyclopentanoids
Singh, Bara,Bankar, Siddheshwar K.,Ramasastry
supporting information, p. 1043 - 1048 (2022/02/05)
We describe the palladium-catalyzed Nazarov-type cyclization of easily accessible (hetero)arylallyl acetates to pentannulated (hetero)arenes. This method provides ready access to various types of bi-, tri-, tetra-, and pentacyclic cyclopentanoids under ne
Transition metals in organic synthesis, part 96. First total synthesis of streptoverticillin: Unambiguous confirmation of the absolute configuration
Thomas, Claudia,Kataeva, Olga,Kn?lker, Hans-Joachim
scheme or table, p. 2663 - 2666 (2011/12/04)
Using an iron-mediated construction of the carbazole framework, the first synthesis of streptoverticillin is described and the absolute configuration of the natural product is confirmed. The synthesis exploits a novel oxygen-mediated aromatization of tric
A direct palladium-catalyzed route to selectively substituted carbazoles through sequential C-C and C-N bond formation: Synthesis of carbazomycin A
Della Ca', Nicola,Sassi, Giovanni,Catellani, Marta
supporting information; experimental part, p. 2179 - 2182 (2009/10/02)
The present paper offers a synthetically simple one-pot procedure for the catalytic preparation of the biologically interesting class of carbazoles. The new procedure is based on the combined catalysis of palladium and norbornene starting from o-substituted iodoarenes and N-sulfonylated or N-acetylated o-bromoanilines. A well-known member of this class, carbazomycin A, has been successfully prepared.