74867-41-7Relevant academic research and scientific papers
Synthesis of 1,2,3-Decanetriol Stereoisomers
Rinaldi, Peter L.,Levy, George C.
, p. 4348 - 4351 (2007/10/02)
The synthesis and 13C NMR spectra of 1,2,3-decanetriol stereoisomers are described. High enantiomeric purity triols are obtained by chromatographic resolution of diastereomeric carbamates derived from 1-decyn-3-ol and (R)-1-(1-naphthyl)ethylamine. The triol is obtained by conversion of the acetylene to an olefin, stereoselective epoxidation with tert-butyl hydroperoxide and a transition-metal catalyst, and stereospecific ring opening of the epoxide with KOH.
