74879-98-4Relevant articles and documents
Titanium-Catalyzed Intermolecular Hydroaminoalkylation of Alkenes with Tertiary Amines
Geik, Dennis,Rosien, Michael,Bielefeld, Jens,Schmidtmann, Marc,Doye, Sven
supporting information, p. 9936 - 9940 (2021/03/31)
The first cationic titanium catalyst system for the intermolecular hydroaminoalkylation of alkenes with various tertiary alkylamines is presented. Corresponding reactions which involve the addition of the α-C?H bond of a tertiary amine across the C?C double bond of an alkene take place at temperatures close to room temperature with excellent regioselectivity to deliver the branched products exclusively. Interestingly, for selected amines, α-C?H bond activation occurs not only at N-methyl but also at N-methylene groups.
From Internal Olefins to Linear Amines: Ruthenium-Catalyzed Domino Water-Gas Shift/Hydroaminomethylation Sequence
Liu, Jie,Kubis, Christoph,Franke, Robert,Jackstell, Ralf,Beller, Matthias
, p. 907 - 912 (2016/02/18)
A selective ruthenium-catalyzed water-gas shift/hydroformylation of internal olefins and olefin mixtures is reported. This novel domino reaction takes place through a catalytic water-gas shift reaction, subsequent olefin isomerization, followed by hydrofo
Efficient and regioselective ruthenium-catalyzed hydro-aminomethylation of olefins
Wu, Lipeng,Fleischer, Ivana,Jackstell, Ralf,Beller, Matthias
supporting information, p. 3989 - 3996 (2013/04/10)
An efficient and regioselective ruthenium-catalyzed hydroaminomethlyation of olefins is reported. Key to success is the use of specific 2-phosphino-substituted imidazole ligands and triruthenium dodecacarbonyl as catalyst. Both industrially important alip
