748799-86-2Relevant academic research and scientific papers
A convenient protocol for the synthesis of ligands from a 4-methyl-3,5-diacylaminophenyl platform
Pickaert, Guillaume,Cesario, Michele,Ziessel, Raymond
, p. 5335 - 5341 (2007/10/03)
The synthesis of stable and highly organized phenanthroline, terpyridine, and pyridino-oxazoline ligands bearing one or two 4-methyl-3,5-diacylaminophenyl modules equipped with two lateral dialkoxyphenyl groups has been performed using EDC·HCl and DMAP reagents in the final coupling reaction. Evidently, in the final ligands and in the solid state intermolecular hydrogen bonding maintains the coherence of the tridimensional structure as clearly evidenced by FT-IR and X-ray diffraction spectroscopy in the cases of the methoxy ligands. The supramolecular packing is also maintained by additional π-π stacking interactions.
Tuning organogels and mesophases will phenanthroline ligands and their copper complexes by inter- to intramolecular hydrogen bonds
Ziessel, Raymond,Pickaert, Guillaume,Camerel, Franck,Donnio, Bertrand,Guillon, Daniel,Cesario, Michele,Prange, Thierry
, p. 12403 - 12413 (2007/10/03)
A novel family of highly functionalized molecules consisting of a central 4-methyl-3,5-diacylaminobenzene platform linked in close proximity to the methyl group by two lateral aromatic rings each equipped with two long alkoxy chains has been rationally de
