74892-45-8

Basic information

• Product Name: 5-Acetoxymatairesil dimethyl ether
• Synonyms: 5-Acetoxymatairesil dimethyl ether;5-AcetoxyMatairesinol diMethyl ether
• CAS NO: 74892-45-8
• Molecular Formula: C₂₄H₂₈O₈
• Molecular Weight: 444.47432
• Mol File: 74892-45-8.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 5-Acetoxymatairesil dimethyl ether(CAS DataBase Reference)
• NIST Chemistry Reference: 5-Acetoxymatairesil dimethyl ether(74892-45-8)
• EPA Substance Registry System: 5-Acetoxymatairesil dimethyl ether(74892-45-8)

Safety Data

• Hazardous Substances Data: 74892-45-8(Hazardous Substances Data)

Usage

General Description

5-Acetoxymatairesil dimethyl ether is a chemical compound with the molecular formula C11H24O5Si. It is a derivative of matairesinol, a natural phenolic compound found in plants. 5-Acetoxymatairesil dimethyl ether has a molecular structure with two methyl groups, an acetoxy group, and a siloxy group attached to the matairesinol backbone. 5-Acetoxymatairesil dimethyl ether is commonly used in organic synthesis and chemical research as a building block for the production of various organic compounds. It has potential applications in the development of new pharmaceuticals, agrochemicals, and materials. Additionally, it may have biological activities and potential commercial uses in the future.

Upstream product

• 81623-30-5 (-)-(7R,8R,8'R)-4,4',7-trihydroxy-3,3'-dimethoxylidnano-9,9'-lactone 
• 108-24-7 acetic anhydride 
• 69586-96-5 5-hydroxymatairesinol dimethyl ether 

Relevant articles and documents

Introduction of an Alcoholic Hydroxyl Group into 2,3-Dibenzylbutyrolactone Lignans with Oxidizing Agents and Carbon-13 Nuclear Magnetic Resonance Spectra of the Oxidation Products

Attempts were made to introduce an alcoholic hydroxyl group stereospecifically at the C-5 or C-6 position of 2,3-dibenzylbutyrolactone lignans with lead tetraacetate and osmic acid as oxidizing agents. 5-Acetoxyarctigenin monoacetate (III) was obtained from arctigenin monoacetate (II), 5-acetoxyisoarctigenin monoacetate (XIII) from isoarctigenin monoacetate (XII) and 5-acetoxytrachelogenin diacetate (XXIII) from trachelogenin diacetate (XXII) by oxidation with lead tetraacetate in acetic acid. 6-Hydroxyisomethyltrachelogenin (XXXII) was obtained from 3-(3,4-dimethoxybenzyl)-2-(3,4-dimethoxybenzylidene)butyrolactone (XXXI) by oxidation with osmic acid.The 13C-NMR spectra of these oxidation products and analogs are discussed with regard to the differences of the chemical shifts resulting from changes in the substituents and the stereochemistry of the 2,3-dibenzylbutyrolactone skeleton.Keywords - 2,3-dibenzylbutyrolactone lignans; reaction with oxidizing agents; introduction of an alcoholic hydroxyl group; 5-hydroxy-2,3-dibenzylbutyrolactone lignans; 2,5-dihydroxy-2,3-dibenzylbutyrolactone lignans; 2,6-dihydroxy-2,3-dibenzylbutyrolactone lignans; 13C-NMR