749175-42-6

Basic information

• Product Name: 2H-Pyran-2-carboxylicacid,5-aminotetrahydro-,cis-(9CI)
• Synonyms: 2H-Pyran-2-carboxylicacid,5-aminotetrahydro-,cis-(9CI)
• CAS NO: 749175-42-6
• Molecular Formula: C6H11NO3
• Molecular Weight: 145.16
• Product Categories: AMINEPRIMARY;CARBOXYLICACID
• Mol File: 749175-42-6.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 308.4±42.0 °C(Predicted)
• Appearance: /
• Density: 1.237±0.06 g/cm3(Predicted)
• PKA: 3.19±0.20(Predicted)
• CAS DataBase Reference: 2H-Pyran-2-carboxylicacid,5-aminotetrahydro-,cis-(9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 2H-Pyran-2-carboxylicacid,5-aminotetrahydro-,cis-(9CI)(749175-42-6)
• EPA Substance Registry System: 2H-Pyran-2-carboxylicacid,5-aminotetrahydro-,cis-(9CI)(749175-42-6)

Safety Data

• Hazardous Substances Data: 749175-42-6(Hazardous Substances Data)

Upstream product

• 603130-20-7 4-nitro-benzoic acid 2-(tert-butyl-dimethyl-silanyloxymethyl)-3,6-dihydro-2H-pyran-3-yl ester 
• 603130-21-8 2,2,2-trichloro-acetimidic acid 2-(tert-butyl-dimethyl-silanyloxymethyl)-3,6-dihydro-2H-pyran-3-yl ester 
• 603130-22-9 N-[6-(tert-butyl-dimethyl-silanyloxymethyl)-3,6-dihydro-2H-pyran-3-yl]-2,2,2-trichloro-acetamide 
• 603130-23-0 (2S,5S)-5-[(tert-butoxycarbonyl)amino]-2-[(tert-butyldimethylsilanyloxy)methyl]-2,5-dihydro-6H-pyran 
• 603130-24-1 ((3S,6S)-6-Hydroxymethyl-tetrahydro-pyran-3-yl)-carbamic acid tert-butyl ester 
• 2873-29-2 D-glucal triacetate 
• 273199-64-7 (2R,3R)-2-[(tert-butyldimethylsilanyloxy)methyl]-3-hydroxy-3,6-dihydro-2H-pyran 
• 132375-36-1 6-O-(tert-butyldimethylsilyl)-1,5-anhydro-2,3-dideoxy-D-erythro-hex-2-enitol 
• 149342-25-6 ((2R,3S)-3-acetoxy-3,6-dihydro-2H-pyran-2-yl)methyl acetate 
• 125901-90-8 (2R,3S)-2-(hydroxymethyl)-3,6-dihydro-2H-pyran-3-ol 
• 603130-25-2 (2S,5S)-5-[(tert-butoxycarbonyl)amino]tetrahydropyran-2-carboxylic acid 
• 603130-11-6 (2S,5R)-5-[(tert-butoxycarbonyl)amino]-2-[(tert-butyldimethylsilanyloxy)methyl]-2,5-dihydro-6H-pyran 
• 603130-12-7 1,5-anhydro-2-[(tert-butoxycarbonyl)amino]-2,3,4-trideoxy-D-erythro-hexitol 
• 199801-81-5 N-((3R,6S)-6-(((tert-butyldimethylsilyl)oxy)methyl)-3,6-dihydro-2H-pyran-3-yl)-2,2,2-trichloroacetamide 

Relevant articles and documents

Synthesis of novel tetrahydropyran-based dipeptide isosters by overman rearrangement of 2,3-didehydroglycosides

Differently functionalized tetrahydropyran-based dipeptide isosters have been efficiently synthesized from 3,4,6-tri-Oacetyl-D-glucal. Analogues of the hsp65 p2-13 epitope of Mycobacterium tuberculosis and Mycobacterium leprae were prepared by replacement of the Ala-Tyr or Glu-Glu moiety in the native dodecapeptide with the prepared dipeptide isosters. Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003).