74927-37-0Relevant articles and documents
Diastereoselectivity Enhancement in Vinylcuprate Addition to β-Alkoxyaldehydes Via a Vinylsilane.
Burke, Steven D.,Piscopio, Anthony D.,Marron, Brian E.,Matulenko, Mark A.,Pan, Gonghua
, p. 857 - 858 (1991)
The presence of a removable 1-(trimethylsilyl) residue greatly increases the chelation-controlled diastereoselectivity in alkenylcuprate additions to chiral β-alkoxyaldehydes.Several methods for protiodesilylation of the resultant allylic alcohols 2b (R=Me3SiCH2CH2OCH2-, PhCH2OCH2-, and PhCH2-)> are compared.