74953-38-1Relevant articles and documents
Deconstructing the Catalytic, Vicinal Difluorination of Alkenes: HF-Free Synthesis and Structural Study of p-TolIF2
Sarie, Jér?me C.,Thiehoff, Christian,Mudd, Richard J.,Daniliuc, Constantin G.,Kehr, Gerald,Gilmour, Ryan
, p. 11792 - 11798 (2017)
Recently, contemporaneous strategies to achieve the vicinal difluorination of alkenes via an I(I)/I(III) catalysis manifold were independently reported by this laboratory and by Jacobsen and co-workers. Both strategies proceed through a transient ArI(III)
A practical synthetic method of iodoarene difluorides without fluorine gas and mercury salts
Sawaguchi, Masanori,Ayuba, Shinichi,Hara, Shoji
, p. 1802 - 1803 (2007/10/03)
Iodoarene difluorides were synthesized in three steps from the corresponding iodoarenes without the use of dangerous reagents such as fluorine gas of harmful mercury salts.
Electrochemistry of Hypervalent Compounds. 6. Selective α-Fluorination of Sulfides Using Electrogenerated Hypervalent p-Methoxyiodobenzene Difluoride
Fuchigami, Toshio,Fujita, Toshiyasu,Higashiya, Seiichiro,Konno, Akinori
, p. 131 - 133 (2007/10/03)
Anodically generated hypervalent p-methoxyiodobenezene difluoride reacted with α-(arylthio)- and α-(benzylthio)acetates, and α-(phenylthio)acetophenone to provide the corresponding fluorinated compounds. In all cases, a fluorine atom was introduced exclus
Electrolytic Partial Fluorination of Organic Compounds. 14. The First Electrosynthesis of Hypervalent Iodobenzene Difluoride Derivatives and Its Application to Indirect Anodic gem-Difluorination
Fuchigami, Toshio,Fujita, Toshiyasu
, p. 7190 - 7192 (2007/10/02)
The electrosynthesis of hypervalent iodobenzene difluorides was accomplished by anodic oxidation of p-nitro- and p-methoxyiodobenzenes with Et3N*3HF in anhydrous acetonitrile, and p-methoxyiodobenzene difluoride was used as a mediator for indirect anodic
SYNTHESEN VON ARYLJOD(III)-DIFLUORIDEN DURCH DIREKTFLUORIERUNG VON ARYLJODIDEN
Naumann, D.,Ruether, G.
, p. 213 - 222 (2007/10/02)
The aryl iodides C6H5I, o-XC6H4I(X = F, I), m-FC6H4I and p-XC6H4I (X = F, Cl, Br, I, CH3, NO2) react with elemental fluorine at about -100 deg C in CCl3F to form the corresponding aryl iodine difluorides without attack on the aromatic ring.Preparations, (