74963-70-5Relevant academic research and scientific papers
Simple total syntheses of biologically active pentathiadecane natural products, 2,4,5,7,9-pentathiadecane 2,2,9,9-tetraoxide (dysoxysulfone), from Dysoxylum richii, and 2,3,5,7,9-pentathiadecane 9,9-dioxide, the misidentified lenthionine precursor SE-3 fr
Block,De Orazio,Thiruvazhi
, p. 2273 - 2275 (2007/10/02)
Brief total syntheses are reported for 2,4,5,7,9-pentathiadecane 2,2,9,9-tetraoxide (dysoxysulfone, 1), from the Fijian tree Dysoxylum richii, 2,3,5,7,9-pentathiadecane 9,9-dioxide (8), from shiitake mushroom (Lentinus oedodes), and 2,4,5,7-tetrathiaoctan
The structure of an unusual disulfide, formed from reaction between a sulfene-amine zwitterion and thionyl chloride
Grossert, J. Stuart,Bharadwaj, Madan M.,Faught, J. Brian,Terzis, Aris
, p. 1106 - 1110 (2007/10/02)
Thionyl chloride has been shown to react with the zwitterion from dimeric sulfene and triethylamine to give bis(methylsulfonyl dichloromethyl) disulfide, 3.The structure of 3 was determined from its spectral properties and was confirmed by an X-ray crystal structure analysis.Dechlorination of 3 gave bis(methylsulfonylmethyl) disulfide, 4.Raman spectra of 3 and 4, as well as of 5 and 6, two related sulfones derived from 2,4,6-trithiaheptane, are reported.
