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Reactions of Terminal Alkynes with Iodine in Methanol
Heasley, Victor L.,Shellhammer, Dale F.,Heasley, Lynn E.,Yaeger, David B.,Heasley, Gene E.
, p. 4649 - 4652 (1980)
Terminal alkynes 1-hexyne (1), tert-butylacetylene (2), and phenylacetylene (3) react with iodine in methanol to give only 1,2-diiodoalkenes.If the reactions are carried out in the presence of silver nitrate, however, diiodo ketones (RC(O)CHI2) and substi
