74973-33-4

Upstream product

• 130820-51-8 3-(4-methoxyphenyl)-1-(3-methoxyphenyl)-2-propene-1-one 
• 1774-47-6 trimethylsulfoxonium iodide 
• 80981-84-6 4-Methyl-N-(2-oxo-ethyl)-N-(3,4,5-trimethoxy-phenyl)-benzenesulfonamide 

Downstream Products

• 76934-64-0 4-Hydroxy-4-(4-methoxy-phenyl)-1-(3-methoxy-phenyl)-butan-1-one 
• 74973-40-3 7-methoxy-4-(4-methoxyphenyl)-3,4-dihydronaphthalen-1(2H)-one 
• 74973-39-0 5-Methoxy-4-(4-methoxy-phenyl)-3,4-dihydro-2H-naphthalen-1-one 
• 78074-35-8 4-(4-Methoxy-phenyl)-1-(3-methoxy-phenyl)-butan-1-one 

Relevant academic research and scientific papers

Visible-Light Induced Direct Synthesis of Polysubstituted Furans from Cyclopropyl Ketones

In this article, a photoredox protocol for the synthesis of furans via oxidative coupling of olefin generated in situ from cyclopropyl ketones with ketonic oxygen atom is presented. Moreover, bromination of furans in the presence of overstoichiometric oxidant has been achieved with high regioselectivity.

Reactions of Aryl Cyclopropyl Ketones. A New Synthesis of Aryl Tetralones

Aryl cyclopropyl ketones (2) cyclise to 1-tetralones (3) in the presence of a variety of acid catalysts under mild conditions.Open-chain carbinols (4) are also formed.The ratio of (3) to (4) is dependent on the aryl ring substituents.A cationic mechanism is proposed.Cyclopropyl ketones (1) do not react.Stereoelectronic factors involved in the reactivity of the rigig cyclopropyl ketone (12) are discussed.The reactions of selected phenolic cyclopropyl ketones have been investigated as anionic counterparts to the acid-catalysed reactions.No reaction is observed.